투고논문
| JKRMS Volume 28, No 4, pp 38, H-D exchange of pyrrolic NH prot... | |
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| 2024년 12월 20일 / 조회수: 204 | |
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H-D exchange
of pyrrolic NH protons prompted by fluoride in aprotic DMSO-d6 Sung Kuk Kim* Department of Chemistry and Research Institute of
Natural Science, Gyeongsang National University, Jinju 52828, Republic
of Korea Received Nov 12, 2024; Revised
Nov 27, 2024; Accepted Nov 28, 2024 Abstract The binding feature of bipyrrole-strapped calix[4]pyrrole 1
for the fluoride anion was examined by a combination of 1H and 19F
NMR spectroscopy in DMSO-d6 . Receptor 1 was found to
bind the fluoride anion with high affinity via two step-process. Fluoride
binding to receptor 1 was proved to facilitate deuterium exchange of the
pyrrolic protons in the nominally aprotic deuterated solvent of DMSO-d6. Keywords Fluoride, deuterium
exchange, anion receptor, calix[4]pyrrole, aprotic solvent
* Address correspondence to: Sung Kuk Kim, Department of Chemistry and Research Institute of Natural Science, Gyeongsang National University, Jinju 52828, Republic of Korea. Tel: 82-55-772-1494; E-mail: sungkukkim@gnu.ac.kr |
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| 첨부파일 | 2. JKMRS_KimSK_pp38-43.pdf |